Plenty of good comments above.
Doubles can be a double edged sword if you rely on them but don't understand them.
Pretty simple in the big picture though.
80's are one thing, jump to steel and you need to rethink buoyancy and the respective redundancy on that.
Then there is the gas management of extended time and either lost deco or lost backgas (which is where your instructors concerns may have come from depending on where you are, I didn't read the thread too closely, so sorry if I missed anything).
Nuff said...
Edit: Sorry, I read again and saw 36-40%. So you can't get too crazy with that high O2 without other issues that you already know about from Nitrox use.
DIVE PLAN
Surface interval = 5 day 0 hr 0 min.
Elevation = 0ft
Conservatism = + 2
Dec to 70ft (1) Nitrox 38 50ft/min descent.
Level 70ft 68:36 (70) Nitrox 38 1.18 ppO2, 48ft ead
Asc to 20ft (71) Nitrox 38 -30ft/min ascent.
Surface (72) Nitrox 38 -30ft/min ascent.
OTU's this dive: 92
CNS Total: 32.5%
155.1 cu ft Nitrox 38
155.1 cu ft TOTAL
That plan is an expended set of AL80s at 3000 at .7 RMV
There are infinite combinations of Mix/depth/Time/BlahBlah. You need to understand what you are doing.
If you have to ask, Stop, some mentoring/training might be in order. Sorry to sound harsh, but I have not seen a way to delete a post on this site, so it's here for life, just cleaning up after myself.
No super deal breaker, just be warned. Heck there is no law that I know of that requires certification, But it is generally a good thing.
But I agree that the Nitrox/Doubles thing is sort of bogus. Nitrox passing NDL or past CESA depth or overhead is another story.