Every 300 bar din valve I've ever seen has a relief hole in the side. This is primarily to prevent a 200 bar reg from pressurizing at all. The short 200 reg won't seat the Oring and the when you turn on the valve it vents out the small hole just ahead of the oring sealing surface. If you pressurize a SS din plug in a 300 bar you only need to back it out a little to uncover this small hole.
I've seen some 200 bar din valves (all my thermos) that have the small vent, and some, DiveRite for example that do not.
I suppose that one could have a problem removing a SS din plug from a unvented 200 bar, both in terms of thread damage, and some small risk to personel from the plug itself, but in practice I doubt. The threads themselves aren't going to be gas tight for long, just back off the Din Plug a little and wait, the tiny volume of gas trapped in the valve will bleed off through the threads.
Tobin