At the advanced nitrox level you will be diving to a maximum of 150' and in that depth range both 100% and 50% work ok and which one is ideal may depend on the dive and where you are diving.
Consider a 150' dive on 25% nitrox:
With 50% for a deco gas you will have 35 minutes of deco (65 min run time) and with average bottom and deco RMVs you will use around 116 cu ft of back gas and 31 cu ft of deco gas.
With 100% for a deco gas you will have 33 minutes of deco (63 min run time) and with average bottom and deco RMVs you will use around 136 cu ft of back gas but you will use only 11 cu ft of deco gas.
The run time differences are minor, but the difference in back gas used with 100% can be significant, especially if you push the run time out another 5 minutes. In that case you have a 76 min run time with O2 and use 160 cu ft of back gas compared to an 80 minute run time and only 138 cu ft of back gas with 50%. So while the run time differences are minor, the need to do all the stops below 20' on back gas will mean you use a lot more back gas and that can begin to become a limiting factor before it would with 50%.
Another serious consideration can be the CNS percentage incurred on the dive. The comparatively long stops at 10 and 20 feet on O2 will use result is as much CNS impact as the entire bottom portion of the dive and the CNS percentages will be significantly greater than with 50%.
So, for offshore diving in the 100-150' range, 50% for deco makes a great deal of sense.
On the other hand, in N Florida cave country O2 is very common as deco is more likely after something like a 70 ft for 90 minute profile or a 100 ft for 60 minute profile where the total deco may be only 15 minutes with most of it at shallow stops - and where deeper stops won't really fit the cave profile and may not allow you to use 50% efficiently.
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Once you go beyond the 150' limit, the picture will start to look different. Consider a 200' dive for 30 minutes on 18/35 where RMVs etc are otherwise equal to the 150' dives above.
With 100% only, you would have a 100 minute runtime and use 223 cu ft of back gas - not a viable option if you have only 260 cu ft of back gas as it does not leave an adequate reserve - and 31 cu ft of O2.
With 50% only you have a 108 minute run time and use only 165 cu ft of back gas, but 62 cu ft of 50%. In this case you are cutting the deco gas close in terms of a reserve.
So again, the run time differences are minor but the gas planning implications are significant.
There are also lost gas considerations and that, along with longer single gas run times, argues heavily for two deco gases.
On the same dive, to 200' for 30 minutes but with both 50% and 100%, you will have a 92 minute run time, use only 165 cu ft of back gas, 25 cu ft of 50% and 23 cu ft of 100%. So an AL 80 of 50% and an AL 40 of 100% would be all you need to cover the dive plus the loss of a single deco gas.
That is also where it starts getting interesting and controversial. Consider the same dive but with 32% for a travel/deco gas along with 80% for a deco gas. You will get a 90 minute run time, use only 148 cu ft of back gas, 29 cu ft of 32% and 32 cu ft of 80%. It works well when everything goes as planned. However you are then right on the edge with the lost single lost gas scenarios unless your deco RMV is pretty good (.4 cfm or below). The advantage is that 80% has a significantly smaller CNS percentage than 100% O2 on the same dive and with a MOD of a 33' it is much friendlier offshore where you may prefer to do the last stop at 20'.
Once you get deeper and use mixes with greater amounts of helium, isobaric counter diffusion begins to be an issue, so the travel gas/first deco gas will need to have some helimum in it and a single deco gas is just not an option.
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Back in the day when I took advanced Nitrox and deco procedures, TDI taught the use of two gasses as well as deco mixes up to 100% while IANTD limited you to one gas and 50%. With that in mind the TDI course allowed the diver to start getting comfortable with 2 deco bottles or a travel gas and deco gas as well as allowing the diver tyo use 100% for 02. In my opinion, the greater flexibility of the TDI left the diver better prepared for both offshore and cave diving in the 100-150' depth range and makes the transition to normoxic trimix a bit easier. But - check the current standards as things do change.
In any event, buying an AL 80 and an AL 40 with regs suitable for high percentage O2 use will leave you well prepared for pretty much anything you will encounter down to 200' or so.