30 to 40. anything over that. Get suited up for doubles. SLing the redundant air supply. avoid the word PONEY as it is a bad word and miss understood...
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I dive with an 80 cf foot "pony bottle". It also has a human brain that comes with it to assure that decisions are sound when things get stressful. In fact, it has an "auto-deploy" feature that actually puts the regulator in my face if I make a certain signal.
For < 100' a 19 cf would probably be adequate, but I'd recommend a 30 cf or even a 40 cf. A 30/40 would be workable even if it isn't full, isn't much bigger than a 19 and I'd consider it mandatory when you do venture into the 100-130' range.