wedivebc:
The question I want to know the answer to from a thinking diver, not a GI sock puppet is why is 80% at 30ft any less valuable than 50% at 70ft or any other gas breathed at it's highest acceptable ppo2?
80% is theoretically less useful than 100% due to the efficiency of offgassing gas held in solution. Note that 30 fsw has little to do with it. While ppo2 1.6 is achieved with 80% at 30 fsw, and earlier than on 100%, the point is that to release gas held in solution it is necessary to ascend.
The rate at which molecular gas transfusion occurs across a semipermiable membrane is driven (primarily - forgive my simplification) by relative molecular 'density' on both sides of the semipermiable membrane. There are two factors that account for a great deal of that relative 'density'. These are the ambient pressure, which determines the rate at which gas comes out of solution or tissues; and the gas being breathed - which determines how much N2 exists on one side of the semipermiable membrane.
In order to theoretically achieve the "cleanest decompression possible", one would want to reduce N2 to zero on one side of the semipermiable membrane, while reducing ambient atmospheric pressure at a rate that maintains as high a molecular density on the other side of the membrane as possible without actually incurring DCI. This is the "gradient" referred to in the RGBM model. The magnitude of the variance between the two sides of the membrane determines how 'steep' the gradient is. The greater the magnitude of the variance, the more rapid and 'complete' the offgassing, or movement of gas molecules from one side to the other.
The former is accomplished by breathing a gas without any N2 in it. The latter is accomplished by controlling rate of ascent, and in particular, ascent during the 50% reduction from 2 ATA to 1 ATA (or from ~33 fsw to the surface). As the diver ascends, gas continuously comes out of solution - too slow an ascent is as unhelpful with respect to cleanest decompression as too fast.
(Thus, breathing 80% at 30 fsw with ppo2 1.6 would be valuable
at that depth. To achieve "cleanest decompression", however, one would eventually need to ascend to release gas held in solution. At which point an 80% deco gas would no longer provide an optimal gradient...)
In other words, to optimize efficiency of offgassing of what Weinke refers to as "a critical volume of bubbles or separated gas" (2003, p.274) it is essential that the diver maintain N2 coming out of solution at high volume (on the arterial side of the membrane) and the N2 level at lowest volume in the lungs (which would result from breathing a gas that does not contain N2).
Note that I've mentioned the word "theoretical" a number of times.....
While AFAIK O2 does indeed provide a cleaner decompression in a shorter time, it is not without it's drawbacks.
Most software, to include V-Planner and D-Plan, will yield runtime increases of less than 4-5 minutes overall resulting from the use of 80% instead of O2 (for the depths and runtimes that the majority of SB divers would be doing. Very few of us, if any, are routinely going "downtown" with George...).
Use whatever you want to use. In the 1980's I routinely decompressed on air using Canadian military decompression tables when diving in Lake Superior. Astonishingly, I continue to live. Very few people will give a crap what you use to decompress with.
The single exception is if you are diving with a team. If you are diving with a team it makes a great deal of sense, logistical and otherwise, to all use precisely the same gasses throughout the dives. If you find this problematic, then don't dive with the team.
Hope this helps.
Doc
P.S. The above generally comes from Weinke, B.R. "Basic Decompression Theory and Application" Best Publishing 2003, in particular, pages 266-275. Any mistakes in comprehension are naturally my own. I recommend that anyone interested buy the book and read it. Even if you are not into the math, just by carefully reading the text you can pick up what Weinke is saying. While Weinke is not without his critics, AFAIK he represents cutting edge in terms of explicating theoretical behaviors of gas in solution, bubble formation, and the process of on-gassing and off-gassing while diving. FWIW. YMMV.