I use a 13 or a 6 cu-ft pony bottle. I ran "out" on a high exertion, solo dive in 130 a few years ago (operator error). I was extremely winded and did not realize my predicament until it was getting hard to breath. I was using a 6 cu-ft pony and immediately started an ascent.. 15 feet off the the bottom - I dropped a piece of gear.. I watched it sink away as I cussed myself for not using a 13 cu-ft bottle which would have allowed me to chase it.. it was lost.
On the ascent, I tried to use the buoyancy of the BC, refrained from kicking and tried to slow my breathing rate as much as possible. I probably ascended at 60 FPM and when I got to 30 feet, I stopped, switched to the primary (steel tank) and did my 3 minute stop from 30 to 10 feet.
I am comfortable using a 6 cu-ft to about 100 feet, but the reality of the matter is that you MUST begin the ascent immediately. If you want to "dick around" on the bottom for a minute or more - then you want a bigger pony.
If you are willing to ascend immediately and at an initial rate of maybe 60 feet per minute, then a 6 cu-ft tank should get you out of trouble. If you are diving at 100 feet, one minute should put you at a depth of around 40 feet, and from there you can slow/suspend the ascent and try to avoid getting the bends. I am perfectly willing to dive with those constraints (at depths of around 100 ft); also I know I can make a free ascent from 40 feet if I am even slightly buoyant.
The important thing is to do the math for yourself. Make mathematical/situation assumptions that you are willing to bet your life on. Also, as illustrated in my stupid human trick described above... if you simply run low on air at depth- if you switch to a pony and then make it to 20 or 30 feet and you are calm.. then you can sip that "MT" tank for quite a long time. If you blow a hose or lose all your air - well then that scenario is no longer a relevant assumption.
Which concludes my off topic rant.. if you want to back mount the pony.. this is the BEST way that I know.. cheap too.
[video=youtube_share;j0sdSL-ng-g]http://youtu.be/j0sdSL-ng-g[/video]