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This is not a good idea nor is it the point in a pony bail out.....Another idea to just throw out there. Since you've already got the extra hardware why not learn to properly side-mount it with your other tank? That way you can go ahead and breath that extra 40 cubic feet (instead of just dragging dead weight around) while still having the redundancy. Assuming you use a AL80 or something normally you'll be somewhat lopsided but hey, no worst than side-mounting a single tank.
DIY sidemount kits are easy enough to make if your worried about harness costs.
I know there's so many threads about this but most are about ppl thinking to buy one. My friend had one in his closet that he never uses and said here you go. It's essentially new old stock luxfer al40. He bought it new ten years ago and hasn't dove it once. Needs a hydro has a pro valve. I'd like to start diving great lakes wrecks. And want a redundant supply for emergency only. I was originally thinking of buying a 30. But free is free. should I just use it or would I be better off posting it local and see if there's anyone out there who wants to trade a good 30 for a 40 ?