What h90 said in post #8. Ideally, you would use the richest blend (i.e., the highest O2 percentage) possible for the depth of the dive you will be executing. But this only works if you are able to order a specific blend to be custom made for you. You will find the formulae for calculating the best mix in the second half of the Nitrox textbook.
In practice though, one of two blends is most commonly available--32% for deeper dives and 36% for shallower dives. Blending stations typically keep lots of pre-filled tanks of these blends on hand and you can just walk in and pick one up. Since 32% will take you to the recommended recreational limit of 100 ft at a pO2 of 1.4 and all the way to the contingency depth limit of 130 feet at the contingency pO2 of 1.6, this is the most common blend as it works for all recreational diving depths. Here in Thailand, if you just ask for "Nitrox" you get 32%, especially since our dive sites tend to range from the shallows to rather deep, and we don't have to worry that divers will violate their MODs.
However, if you know you will be doing a bunch of somewhat shallower dives and want to cut down on the nitrogen loading with a richer blend, it's possible to ask for 36% and the blending station will probably have pre-filled tanks ready to pick up.
Alternatively, if you want the ideal blend for a dive you are planning, you will have to ask to have your tanks blended to order, which takes time and may cost more.