Try thinking about it this way:
- Your tissues want to be saturated (in equilibrium) to the ambient pressure
- On-gassing happens when the ambient pressure is higher than the gases in your tissues
- Off-gassing happens when the ambient pressure is lower than the gases in your tissues
- This process takes time, the speed depends on the type of tissues
- By changing the ambient pressure (i.e. changing depth), you control how these processes happen
At 20m / 60 feet (3 ATA), the ambient pressure is tripled from sea level. You actually have to stay at that depth for a long time before all your tissues are saturated (some are slower than others). So if you do a quick bounce dive to 20m, and then ascend to 10m, your tissues will not have time to get saturated to 20m or even 10m. So that means when you arrive at 10m your tissues will still be on-gassing. As you ascend, you will hit a depth where some tissues are saturated (no longer on-gassing) and others are still on-gassing, and if you continue to ascend you will hit a depth where some tissues are supersaturated (higher pressure of gases in your tissues than ambient pressure) which means they will start off-gassing. So you can have different tissues in any combination of these 3 different states: on-gassing, saturated, off-gassing.
Also:
Since off-gassing the slower tissues takes time, it's not realistic to stay underwater long enough and have a slow enough ascent that your tissues will be fully saturated to sea level when you surface. Some of your tissues will stay supersaturated (off-gassing) for several hours after an NDL dive. The amount of supersaturation is what the NDL tables/computers control, so that you can ascend directly to the surface at any point in the dive without unecessary risk of DCS. With deco diving it's the same thing, you do decompression stops to make sure your tissues never exceed a certain predetermined level of supersaturation on the ascent. But some tissues will still off-gas for hours after a dive. Which is one of the reasons for surface intervals, time before flying, exercising etc.