Be careful with that: changing one parameter to make things 'more conservative' does not necessarily make things 'more safe'.
Same here. Diving Nitrox is balancing two risks: DCS/Narcosis (caused by the Nitrogen) and OxTox (caused by the Oxygen). Reducing one necessarily increases the risk in the other.
This isn't exactly true, because the two risks aren't dependent on the gas mix in the same way. The risk of CNS oxtox is practically nonexistent for a recreational diver below a ppO2 of 1.4. The risk of DCS increases with time and exposure to ppN2.
Using 36% nitrox on a dive to 70 feet for a second dive of the day will greatly reduce the chance of DCS (compared to using air for the same dive), while exposing the diver to a ppO2 of 1.1... and virtually no risk of CNS oxtox (compared to the ppO2 of 0.65 were the diver to use air.)