Are you an hyperbaric doctor, for saying that exposure to high pressure Nitrogen is more toxic than Oxygen?
The risk of decompression sickness is proportional to how close you go to the NDA limit, not to the partial pressure of Nitrogen.
So, if I always end the dive with adequate conservatorism (say, at 75% of the NDL time limit), there is no substantial advantage breathing an enriched mixture.
Nitrogen is an inert gas, it does not cause significant damage to human cells, even at relatively high partial pressure.
On the other side, high partial pressure of oxygen causes a lot of damage to human cells, and the exposure time is longer (thanks to the extended NDL).
So I leave this approach to others, possibly younger and not so concerned about the toxic effects of oxygen.