I know the theory. I was hoping for some insight into why those specific rates are recommended.It's not just PSI - it's also a recommendation from a number of agencies (TDI, PADI) with respect to blending technique.
Slow fills for O2 prevent compression heating (adiabatic compression) that could result in ignition. The lower the concentration of oxygen - the lower the risk of igniting hydrocarbons or seals in the system. Hence the faster fill rates for lower fractions of O2.
But that is a qualitative argument. And no, I have not seen a quantitative argument to why 60 for O2 is better than 40 or not as good as 100.