So OK... this is going to be like pulling teeth...
You're a male... so you most likely shave which can irritate the peri-oral tissues (around the mouth). You use a "standard" mouthpiece with your regulator... Is it neoprene or silicone? Neoprene is typically
black with a dull surface. Silicone, on the other hand, can be clear but sometimes black and it has a shiny surface texture. If you hood is fabric only, there is no neoprene. However, if
the hood is made of "wetsuit" material, then there is neoprene under the fabric.
What I'm getting at here and the reason I have asked all the questions to to determine if you
may be coming into contact with allergen like neoprene in or around you mouth and if you have
any pre-existing irritation of the skin around the mouth prior to such contact.
Neoprene (synthetic rubber) is a rather common allergen as is latex rubber/latex allergy. Skincontact may result in a rash, itching, peeling, red/irritated skin, runny nose, red,itchy
eyes... even anaphylactic shock. The irritation you described would be common for such a
sensitivity. You might not present with the more serious symptoms.
Obviously, no one can be sure what the actual cause is at this point but a logical cause would be something that touches that part of your face where you are having the problem.
If you want to track this down, then you should try to change to a silicone mouthpiece and if
possible avoid the hood for a few dives and see if the problem disappears.
If you cannot determine if there is neoprene present then simply ask your local dive shop.
Finally, neoprene or some other allergen may NOT be the cause of your problem but you have to start eliminating the usual
suspects. You might have to have a dermatologist look into this matter.