Hi,
I don't know what type of housing you shoot with, but generally speaking, during daylight, I try to shoot at f22-45 to make everything black. Then I put the stobe(s) at an angle that just clears the lens to avoid backscatter. Then get as close as you can, sometimes only afew inches if the fish will let you. If you want to see a pretty good example of what I'm talking about, the opening page of my website has a cowfish with a black background. terrencerossphotography.com There's also a nudibranch, and an octopus that I did using the same technique. The nudibranch was at 8:00 in the morning with bright sunlight.