There is not a "supersaturation point". Tissues have the supersaturation values that they have. It's also not necessarily the tissue with highest tissue tension/pressure. (Faster tissues can handle greater tensions, according to Buhlmann.) There is a GF99 for each tissue compartment, and the controlling tissue is the one with highest GF99.
GF99 = fraction of the tissue pressure from ambient to the M-Value
GF99 = (P_tissue - P_ambient) / (M_value - P_ambient)
(P_xxx is the pressure of that whatever)