I never used steel tanks until I started technical diving, and my instructor was adamant--you never, ever, ever leave boots on steel tanks. I got the idea that they will rust away in a matter of weeks if you do. So when I got my first steel doubles I of course go rid of them.
Years later, I started doing some sidemount, and I bought some LP 85s (Worthington) for that purpose. I also figured I could use them for single tank diving as well. I of course took the boots off, even though I was by then far removed from that original instructor. I took them with me on my annual trip to Florida, where I used them as single tanks for recreational diving off of boats. What a PITA! There was simply no way to keep them stable in their places on the sides of the boats. they were constantly tipping over. They were also a royal pain just getting fills. As soon as I got home, I retrieved the boots. They now only come off when I do my annual visual inspections, and I have never seen a sign of rust when I do those inspections.