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Actually the term "gradient" here is used slightly improperly, as the pressure gradient is the ratio between the pressure difference and the distance "d" of the two points where you did measure the pressure:
grad(p) = (p1-p2)/d
Well, for being pedantic, the gradient is obtained as the limit of the above ratio when d is reduced towards zero...
So the correct wording should have been "pressure difference", not "pressure gradient".
Perhaps this confused some people, also because the term "gradient" is not really of common use outside a physics classroom. "Difference" is much simpler, and maintains the correct meaning...
The limit for avoiding DCS is set on the "pressure ratio", not a "pressure difference" between the pressure of gas inside the tissue and the ambient pressure...Not quite. The Bühlmann (and VPM) model doesn't determine a "safe rate of offgassing" but a safe pressure difference between the pressure of nitrogen (and helium) in the tissue and the ambient pressure at the diver's depth.
Yes, increasing the pressure difference (by ascending to a shallower depth) will increase that rate and exceed the tolerable pressure difference limit, but the rate of offgassing can also be increased safely without ascending by breathing a gas with less nitrogen and helium (and more oxygen). The distinction is subtle but is incredibly important when it comes to choosing deco gasses.
That is in an homogenous medium. But inside the alveoli, we have a liquid in contact with a gas. The Nitrogen leaves the liquid and goes into the gas driven by the pressure difference, NOT by the gradient...
It was a technical example of the colloquial generality that except where more narrowly defined by some particular discipline, gradient and difference can be fairly interchangeable. Beyond that though, the idea that either the tissue compartment model for gas perfusion and DCS risk, or however else you might imagine it works physiologically, does not square with even a more restrictive definition of gradient seems hard to defend. You have physical separation at varying degrees, and perfusion driven in part by concentration differences. That sounds like a gradient (not that you can't also find plenty of examples describing gradient across a membrane). Nothing in the question confined the applicability of the gradient concept entirely to the alveolar interface, even if you think that Henry's law for some reason precludes applicability of the term.That is in an homogenous medium. But inside the alveoli, we have a liquid in contact with a gas. The Nitrogen leaves the liquid and goes into the gas driven by the pressure difference, NOT by the gradient...
Henry's law, not Fick's law...
I understand this entirely, but my point is another: a gradient is a vectorial differential operator, and understanding what a "gradient" is, requires to have studied some advanced physics and maths. Most people do not have this in their background.It was a technical example of the colloquial generality that except where more narrowly defined by some particular discipline, gradient and difference can be fairly interchangeable. Beyond that though, the idea that either the tissue compartment model for gas perfusion and DCS risk, or however else you might imagine it works physiologically, does not square with even a more restrictive definition of gradient seems hard to defend. You have physical separation at varying degrees, and perfusion driven in part by concentration differences. That sounds like a gradient (not that you can't also find plenty of examples describing gradient across a membrane). Nothing in the question confined the applicability of the gradient concept entirely to the alveolar interface, even if you think that Henry's law for some reason precludes applicability of the term.