If you're going to start doubting the accuracy of the analyzers used by your shop, then buy your own. You can be in control of calibration, sensor age, and storage of the unit.
Many shops use a hand held analyzer permanently installed in the system for filling banks. I guess I am not understanding your distrust of analyzers. Most of us calibrate the analyzer in atmospheric air before testing. Sure, it might be off by a few tenths, but unless you're diving serious depth, you're fine.
To be honest, the idea of pushing the recommended limits for the working part of your dives for the purpose of making it easy on you to deal with fills is dangerous and lazy. You're risking your own life and quite honestly the life of your future buddies.
If I remember correctly, you're a very new diver. I'm curious as to your dive experience, certifications and training, and whether you've actually been certified in nitrox. There are a great many divers, both on this board and otherwise, who have decades of experience and the limits currently in use have been well established and the reasons for them well documented.
Permanently marking a tank for anything other than 100% is useless. All shops have a roll of tape & a marker with their analyzer. You're going to analyze & mark them with the actual content anyway. As a rebreather diver, even my diluent tanks are only marked diluent, no content marking is permanent.