Someone else will probably do a much better job at explaining this than I could, but it's really hard to explain without pictures/charts. I'd recommend besides taking the proper deco procedures course which will cover all of this, reading the book deco for divers by mark powell. Excellent easy to read book on decompression theory and why we deco the way we do.
Also check out Dive Rites post Gradient Factors | Dive Rite
Also check out Dive Rites post Gradient Factors | Dive Rite