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That's a pretty weak solution - especially as fast as the vinegar breaks down. I am surprised it worked, doubt that it'd do any good at all with hard, alkaline waters I grew up with. I had a few bad ear infections, but none since I started using equal parts vinegar, alcohol, water as suggested by DocV.U.S. Navy diving and the commercial diving college I managed to live through reccomened a denbromic (sp?) solution of vinigar and water. It is 1 qt. of h2o to 1 tbsp. of vinigar.
The theory is that you don't want to dry the ears out because they are naturally damp. Alcohol removes all the moisture and will result in cracking, pain and other problems. The vinigar solution held for 1 to 5 minutes will kill any bugs you pick up and leave the ear canals moist and clean.
I have never had an exterior ear infection, so I think it works.
No. We have generated a lot of heated air so far which would undoubtedly help by being blown in each ear after a dive.