Gilldiver:Perhaps the real reason some use 80% is that that is just about the highest O2% you can get in a 3000 psi bottle without a boster.
2200 psi O2 (standard max fill for most O2 storage tanks from gas suppliers) topped with 800 psi of air will gived you 80% O2.
Don't let anyone else BS you, if they are using 80% and don't have a booster it is the most they can get.
I get 'T' bottles of aviation grade O2 at about 2600 psi. I keep several around so I can bank them. I get my 80 cu ft decompression bottles up over 2000 psi. That will get you through a VERY long dive. Now if I topped off my O2 bottle with air (mostly nitrogen) I'd have EAN80 LOL but what is all that nitrogen doing for me?
Adding air because you don't have a booster doesn't accomplish anything. I've never done a dive where 50 cu ft of O2 wasn't enough but if I did, I would bring a second bottle of O2 before puming a bunch of nitrogen in.