Not just high concentrations (fO2) but also
high pressures (pO2). When you have a 100% O2 Al 40 tank at
3000 psi and you quickly open the valve to pressurize your unclean reg, you are
increasing the pressure inside the regulator by more than 200 times in just a fraction of a second. That in itself can provide a
good amount of heat in localized areas. Yes, enough heat to ignite silicon grease packed inside an ambient pressure chamber of a piston first stage regulator kitted for cold water diving. It has happened before and probably will happen again.
Changes in pressure also mean changes in other properties such as boiling point or
autoignition temperature. The higher the pressure and the higher O2 concentration, the lower an autoignition temperature becomes.
From
wikipedia (emphasis is mine):
Theoretically, ajduplessis may be right when he says no heat. No heat would mean absolute zero temperature (-273
oC). But I doubt that is what he meant. You lower the autoignition temp enough with high O2 concentrations and pressures, and it could very well end up lower than ambient temperature, which means it'll blow up anytime...