Nitrox or Rescue? That's a no brainer for a new diver. One will increase your bottom time (if no deco-limits are your issue), whilst the other will make you a better diver... All the usual caveats apply (crap instructor, crap course, but that goes for both).
When I am asked about Enriched Air I always ask the divers where are they planning to dive and how are they planning to dive. If you're planning on diving with a dive operator in a group of divers, and on a schedule of 2-3 dives per day when you're on vacation... save your money and don't bother with Nitrox! Most dive operations cater for a lowest common denominator in a group or have a schedule..
I have never had any trouble calling ahead and finding myself an operator to dive with that would let me dive my tanks, and even provide 100s, and sometimes 120s.