You are thinking of a diver's body as if it were one tissue either on gassing or off gassing. When we dive, different tissues absorb nitrogen at different rates, and they off-gas at different rates. When we ascend, the faster tissues will be off-gassing, but slower tissues will still be on-gassing.So above 33FSW a divers body is not off gassing? Why stop at 20FSW for a SS then?
If we do a proper ascent at a proper rate, then enough off-gassing of the tissues will have occurred so that none of them have too much pressure in relation to ambient pressure. A safety stop helps make sure that all tissues are in a safe range. During that safety stop, the faster tissues will continue to off-gas, but the slower tissues will still be on-gassing. Although they are on-gassing, they are still in a safe range relative to ambient pressure.
Off-gassing of all tissues does not begin until the diver surfaces. In the case of technical divers who decompress with oxygen, the faster tissues will actually on-gas during the surface interval.