Derlin/plastic DIN plugs: Pro: will not corrode in the valve no matter how long it's left there. Cons: will not protect valve from deformation, will not retain gas if valve rolls on, worse than useless unless having a hole preventing pressurization, as sudden high pressure plus unrelieved plastic DIN plug can result in high velocity plastic shrapnel.
Chrome-plated brass DIN plugs: Pros: should not corrode in the valve no matter how long it's left there, add a DIN o-ring to it and it will seal in gas if valve rolls on, will provide some protection from deformation if the valve is struck. Cons: will not protect against deformation as well as SS, and is probably too soft to fix mild/moderate deformation, will need a decent wrench to remove if it seals in gas.
SS DIN plugs: Pros: excellent protection of the valve against deformation, and in a pinch may "un-egg" a mildly dented valve if wrenched in and seated completely, add a DIN o-ring to it and it will seal in gas if valve rolls on. Cons: SS and chromed brass will eventually gall the plug into the valve if left long enough, and warm/humid/salt makes the reaction happen faster, will need a decent wrench to remove if it seals in gas, cost a quarter to a half as much as the valve they're in.
Personally, I think the Gulftex or Highland SS plugs are the best, and I just make sure I have an adjustable wrench around if I need to undo a pressurized one. NBD, and I've never seen doing so hurt the threads. Keep extra DIN orings around for them, though, as they tend to get ripped up through the bleed hole when you unscrew the plug.
Brass plugs are theoretically better at avoiding galling, but I've yet to have a problem with SS plugs...then again, I've only left them in for a few weeks/maybe a few months, without removing them. The derlin/plastic plugs are just junk IMO. Without a hole, they're dangerous; with a hole, they're useless at keeping out water/dirt. YMMV.
For DIN regs, I say the delin Highland screw-on DIN caps are the best and even those are not 100% reliable for soaking. The rubber caps like Atomic ships with their DIN regs are for dust, not water of any amount.