A reference for oxygen being toxic and high ppO2s, especially when doing any kind of work, are inherently more risky? Sorry no, not going to play your internet tech instructor.
If you want to run a ppO2 of 1.4 for bottom gas knock yourself out. I gave you a dramatic case of how that can bite you in the butt. I was taught 1.2 for the working phase over 15 years ago (and multiple times since then). 1.6 for deco/at rest.
21/17 @ 150ft (ppO2 1.16) for 20mins has 41 mins runtime (GF 50/80 on EAN50)
25/17 @ 150ft (ppO2 1.38) for 20mins has 39 mins runtime
Your choice saves 2 minutes on the ascent but comes with more risk.
Current standards TDI teaches are 1.4 for working portion and 1.6 for deco.