mikeny9
Contributor
The reason I was bringing up Meyer-Overton is because it makes use of gas solubilities. Helium is indeed less soluble, we can agree on that. What we are at odds with is how Helium reacts in dissolved gas theory. When descending, or more appropriately, when there is a pressure gradient setup between a higher ambient pressure under water and a lower internal pressure of the tissue, the tissue would reach full saturation sooner with Helium that it would with Nitrogen. However, by the same property, it also exits the tissue at the same rate when the opposite gradient is setup, as long as the gas is in free-phase (not dissolved). This is all based on Henry's law. However, since Helium does not dissolve as fast as Nitrogen (about 4.47 times less soluble), gas exits the tissue at a much higher rate than Nitrogen (in theory based on Graham's law.).
The canonical example is the "sugar and sand" scenario. If you pour 1 teaspoon of sugar, simulating Nitrogen, into water at a constant rate until the glass is "saturated", the sugar eventually dissolves because of the solubility of sugar. If you pour 2.65 teaspoons of sand into a glass, simulating Helium (2.65 because that's how Buhlmann would model Helium: moving 2.65 times faster into the tissue) until that glass is saturated, it would saturate much sooner no doubt. However, the sand (Helium) would be able to be removed at the same rate it came into the glass because of it's low solubility, where the sugar (Nitrogen) would have to come out of solution first.
There's also the work done by B.R. Wienke that suggests higher soluble gases causes larger bubbles, and larger bubbles are in theory related to DCS (Buhlmann). (Deep Helium ADVANCED DIVER MAGAZINE By B.R. Wienke and T.R. OLeary)
Keep in mind this is all mad science of decompression theory, i.e. the wild west of the medical research world. We are way off topic from the OP. His original question was if it was "valid" to have tables that use the same NDL (I'm assuming "min-deco limits" means NDL here) for Nitrox 32% as 30/30. In my opinion, it certainly is and is very conservative to do so, based on the theories above.
The canonical example is the "sugar and sand" scenario. If you pour 1 teaspoon of sugar, simulating Nitrogen, into water at a constant rate until the glass is "saturated", the sugar eventually dissolves because of the solubility of sugar. If you pour 2.65 teaspoons of sand into a glass, simulating Helium (2.65 because that's how Buhlmann would model Helium: moving 2.65 times faster into the tissue) until that glass is saturated, it would saturate much sooner no doubt. However, the sand (Helium) would be able to be removed at the same rate it came into the glass because of it's low solubility, where the sugar (Nitrogen) would have to come out of solution first.
There's also the work done by B.R. Wienke that suggests higher soluble gases causes larger bubbles, and larger bubbles are in theory related to DCS (Buhlmann). (Deep Helium ADVANCED DIVER MAGAZINE By B.R. Wienke and T.R. OLeary)
Keep in mind this is all mad science of decompression theory, i.e. the wild west of the medical research world. We are way off topic from the OP. His original question was if it was "valid" to have tables that use the same NDL (I'm assuming "min-deco limits" means NDL here) for Nitrox 32% as 30/30. In my opinion, it certainly is and is very conservative to do so, based on the theories above.
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