Aside from core skills, rebreathers need a certain attitude that is quite pedantic and detail oriented. If you treat a rebreather like I treat my OC kit — roughly and little or no maintenance between dives — a rebreather will kill you without a second thought.
An example. On OC all I do when I get home is shake out and hang up the regs and get more gas for the tanks. OK, I do analyse and mark up the gas after. 5 mins tops.
With the rebreather, I spend at least an hour preparing it the night before a dive using printed checklists. On the boat I’m very particular in running through the pre-dive checklists and pre breathing the unit. Once a week I spend two hours cleaning and disinfecting the rebreather. On the dive I’m very aware of what’s going on and do bubble and bailout checks at the bottom and constantly monitor the vital information on the unit.
OC is simply assemble the kit, turn on the gas, check pressures, breathe, quick pat-down kit check then jump in.
The two diving systems couldn’t be more different.