I was given a tip by my UTD instructior to "palm" the left valve and move it with the underside of your fingers. Think making a C shape with your left hand and pulling and pushing the valve with the C. I never had trouble in the pool, but being a bit chilled after 3 days and 10 or so dives I went for it and struggled... then thought about the tip, and got it turned off and on no problem.
Actually, Justin, he gave me a similar tip a couple of years ago when I was borrowing his 120s for that section of training. I still had a lot of trouble. Then I got my own tanks and realized he had omitted an important step in turning those valves--bring a wrench with you. (He also realized it when he used those tanks himself for the first time and did a valve drill of his own.)
For me, the key changes that helped me were
- Greatly improving my flexibility, which has already been discussed. It took a long time and a lot of patient exercise, but I am now much more flexible in the shoulders than I was before.
- Adjusting my equipment. Lynne once posted a web site that was very helpful in this regard. (I have since lost it, so perhaps she can do it again.) It was really clear to me when looking at people on film doing valve drills effortlessly that my valves were not in the same place their valves were. Making a few adjustments, minor as they were, made a world of difference.