Silicone filled ambient chambers can be a pain from a maintenance standpoint as the silicone can bleed out, particularly in hot weather. The Dow 111 silicone is a little thicker and stays put better in silicone filled environmental chambers. It also sticks a little better to parts in the ambient chamber even if the chamber is not intended to be completely packed.Creed:I looked on scubatools.com, and they have two grades of silicone, 7 and 111. Is there a difference in application?
For internal o-ring lubrication, use the Dow 7 silicone.
Silicone, and Dow 111 in particular, is much more water compatible than ChristoLube which is not well suited at all for use in areas with direct contact to water.
I still use SPEC boots on my personal Mk 20's and fill the chambers with Dow 111 despite using ChristoLube inside the first stages if I am planning to use them nitrox. This does pose the potential for silicone to get into contact with higher levels of O2, but to do so, the silicone would have to migrate upstream past the HP o-ring or past the two piston head o-rings.
I would not recommend it for anyone else or set their regs up for them that way as it is most definitely not SP approved, but so far I have not had any problems. I regard the increased potential for freeze flow in very cold water as a much larger risk than a very small potential for a first stage fire when I pressurize the reg.
There is also potentially some merit in using silicone on some of the o-rings in the second stage that are likely to come into contact with water and will only be exposed to Nitrox at ambient pressure.