Since vO2 is based on the subjects weight it's not actually a good measure of scrubber capacity since my vO2 max could be the same as someone half my weight but I am producing 2x the CO2.
People talk about overbreathing a scrubber, as in you are generating CO2 faster than the rebreather can remove it. That is typically thought to be related to dwell time in the scrubber itself. My issue with that claim is that the scrubbers are tested to breathing rates much higher than normal divers are going to achieve.
For reference. 3cfm, the max that they normally test and what the Navy says all but the most in shape can barely maintain is equivalent to you breathing almost your full lung volume 30x per minute. Try doing that for a minute without passing out.... 1.5cfm is obviously about half that, whether that is 30x half size breaths, or 15x full breaths. Probably doing 30x half breaths in an "excited" situation, vs 15x full breaths when trying to kick really fast if you're in good shape and using rhythmic breathing.
The point of all of this is that "overbreathing" the scrubber is going to be much more related to volume of gas moving through the scrubber which increases the WoB vs the quantity of CO2 in that gas. When you are breathing that hard, the WoB gets worse, when the WoB gets worse, you are going to retain more CO2, when you retain CO2 you start breathing harder. See the failure loop? Once you hop onto OC, the WoB gets better and you are able to get rid of all of that CO2. People talk about that phenomenon as overbreathing the scrubber, as in we are getting CO2 pass through, when the reality is that you are likely just retaining CO2 in your lungs due to your inability to expel it.
@Bobby is big about talking about the "rebreather cough" where it's a good idea when you start feeling that shortness of breath coming to try to cough into the rebreather to get rid of that residual lung volume that is holding the CO2.
Now, what is curious to look at is the duration tests for the O2ptima that I linked above. Those tests are stopped when the CO2 hits 0.5% which is considered normal levels of atmospheric air. It appears that the EAC is unable to scrub as much CO2 at depth and this could well be due to scrubber "breakthrough" as a function of gas density and dwell time where the reaction front appears to get more conical instead of more flat at lower ambient pressures causing the CO2 levels to trip faster.
Clear as mud?