When I decided to get twins, I just did some reading, sites like this really help, there are plenty of threads on the topic. Once I figured out what I needed for gear, I got the stuff together, and set up my doubles.
I'm spending lots of time in doubles at the recreational level before I start with any sort of technical training. I started with the shore dives that I know well, got out and dove the sites the same way I did in a single. It made the change nice and manageable, I did about 30 shore dives in the twins over the winter before I took them on a boat dive.
I had about 90 dives before I made the switch, it took some time to get my routing and configuration sorted out, but like I said, there is lots of info out there. One of my regular dive buddies has his mix card, and he was a great source of advice.
So, asking questions here, and finding someone who dives doubles was a good way to get started for me anyway. I'm sure it will work for you.