I'm not at home but I have a nice recent dive where my petrel was basically diving pure O² at 72m depth
To be honest I'm normally diving it in pure gauge mode and use a table to plan and then align the ascend profile to make it easy to remember. Next I'll also have a ratio on which to fall back if really in the pickle. But these times a very experienced GUE diver asked me to experiment a bit and use it in OC/TECH mode (computer) as a fallback. Also to check if our planning and actual dive runtimes would match the computers expected values.
First dive very nice. However we ended up doing of course deco on 50 and O². Next dive was this 72m dive, and I forgot to switch back from O² to bottom gas (15/55). I only noticed when I arrived on the wreck with the team. Before you're too busy keeping everybody together, gas switch, etc, and with gauge you don't actually need any info at that time. So I noticed at the bottom where I normally take note of descend time, depth, to start calculating avg depht... BIG RED PPO² flashing (I wonder why... with O² at 8+ATA). I kept it flashing for a good 10 minutes just for the fun of it... CNS went through the roof and my deco obligation was a very gentle 3 min at 6m.
I switched to backgas after a while and continued the dive. I forgot what the repercussions where for this DEEP O² dive. I'll look them up on the profile when I get home.
What does happen to me from time to time (just because I'm not used to it in computer mode) is to forget switching to deco gas. This weekend on 2 North Sea wreck dives (50m range), I forgot to switch twice, only doing it after remembering some time into deco (once at 12m, the other at 6m). Funny tho, the total runtime/deco time was not that much off from our plan, even tho I had switched late and had done (in theory on the dc) sub optimal deco partially on backgas. Although probably only about 30% of total deco time.
Never seen it switch automatically but like I said, not that much experience using it as a DC.