Exactly, that's what I was saying.... And it won't pick up breakthrough if the breakthrough is from channeling, right? Only if the sorb itself is being exhausted faster than anticipated.If your CO2 hit had of been as a result scrubber breakthrough the rEvo RMS would have picked it up and given you warning through rapidly dropping remaining scrubber time.
Your hit sounds like more to do with retained CO2, so the rEvo RMS or any scrubber monitoring system would not have picked it up. Maybe a CO2 monitor measuring end tidal CO2 would have given you warning but that technology is not available in rebreathers.
So I think that if you stick to published data, it's unlikely on most dives that the temp stick will alert before you exhaust the scrubber, since that data tends to be so conservative.