I doubt any possibility of a fire,but stranger things has happened.
Why would you be inflating from a deco bottle? I would also assume that when using 50 for this purpose you are ascending? Why the need to inflate if you are going up?
I have learned through this thread that this is being done by some sidemount divers because of the difficulty of carrying a suit inflation bottle. I have never seen it done myself.
I assume it is because they do not want to inflate with the trimix they are breathing. I have had some recent thoughts on that.
I was taught to use a separate suit inflation bottle as soon as i started with trimix. I used argon when I could get it, but it was usually air. I used one on every trimix dive I did for years. A few years, I was setting up my gear on a dive boat during my annual winter stay in Florida, and I overheard a conversation next to me. They were laughing abut the fact that they used to use separate suit inflation bottles. I later took a stroll around the boat. Every diver except me was inflating with back gas.
When I interned on a trimix class pursuant to becoming an instructor, I had to fly to the location. I conferred with the instructor ahead of time about what I needed to bring, what I could rent, and what I could borrow. When I asked about the argon bottle, he almost laughed and told me to use my back gas. He did not own one, either for himself or to loan to me. We did all our dives using back gas, with mixes up to about 60% helium.
This past year when I was in Florida for that annual winter stay and got ready for my first trimix dive, I pulled out my full argon bottle and realized I had left the regulator in Colorado. I dived that day inflating with my back gas, and I did the same on every other dive that winter. I lived. Of course, all the above water temperatures were in the low 70s. Since then, my diving has been in the high 50s, and I have used back gas for that as well. No problem.
I suppose that if I were on a really long dive, it would make a difference.