Dvas,
I'm not sure if I am understanding your question correctly, but I will answer it the way I think you are stating.
If I was diving independant back mounted doubles, I would have both regulator hoses coming over my right shoulder. I would bungy the left tank regulator on a necklace and breathe off of the right tank.
If I was also carrying a stage or deco tank, I would sling it on the left side, with the regulator hose bungied against the tank, where it would be out of the way, yet easy to deploy when needed.
Assuming you were planning on breathing both back mounted tanks, I would breathe the first one down to 2/3 full, then switch regs. You would now be breathing from the left tank, and the right regulator would then be placed in your necklace.
If I was doing a mandatory deco dive, then I would turn the dive when the second tank was down to 2/3 of full and start my ascent.
If you can get one, a good double ender might be useful for clipping off the second reg when you switch to your deco bottle.
I'm sure there may be other ways of doing this, but this seems the most logical way to handle that type of configuration to me.