anzac65:???????????? Mix of gases ? Don't you just get out with a 1 atm lungfull of air and go up like a rocket ? Or have I missed the point ?
The preasure difference between the inside and outside of the sub at 600 ft is about 272 lbs per square inch.
So to open the door and not kill the submariner you need to equalise the preasure in the escape chamber.
If you did not then the water entering the chamber as the door started to open would cut the person inside into little pieces. :no
If you pumped air into the chamber then you will increase the partial presure of O2 well its toxity level. An O2 hit at this depth would not be a pleasent experience.
To overcome this you would need to pump in a mix of Helium, Nitrogen and Oxygen.
Since this would be non-swiming ascent you could take the O2 up to 1.6 or higher, a bit of a gamble but you won't be spending long or working very hard at this depth.
I will let people much more skilled at this work out the optimum mix of gasses and how long it would take to get the escape chamber down to 600 ft.