I would be concirned about breathing "75-80% O2" on a deco-stop. Wouldn't it be possible to know the exact mix you'll be breathing, then calculate stops accordingly?
Pure O2 for deco stops is a good idea, in general, but I'd be reluctant to use an air computer for determining my stops. O2 exposure, residual nitrogen etc. as tracked by the computer will be far off from reality -- and then a good part of the advantage of using a computer is lost. Better, then, to get a set of tables and use them correctly, I think.
Most of all, have fun and be safe