Helium was first proposed for use as a divers breathing gas by Elihu Thomson in a series of letters to W.R. Watson of the General Electric Laboratories in the 1920s. The reason for this was to avoid the limitation on depth that was set by the then-supposed limitation on the
availability of oxygen at depth. The idea was based on the principle of superior rapidity of diffusion of the low density gas [Thompson, E, 1927. Helium in deep diving.
Science, 65,36 38.]
In addition, the physical chemist J. H. Hildebrand suggested to Sayers and Yant of the Bureau of Mines that the lower solubility of helium compared to nitrogen would be of value in preventing caisson disease. They tested this in experiments with guinea pigs. The gas was tested in human experiments by Edger End in 1937 [Rapid decompression following inhalation of helium-oxygen mixtures under pressure.
Amer. J. Physiol, 120, 712 718.] to make its
lower solubility when compared to nitrogen. Theoretically, if a gas did not dissolve at all in a liquid, there would not be any gas at all to form bubbles. In actuality, the difference in solubility between helium and nitrogen is primarily only in lipid (fatty) tissues.
Further, the substitution of helium for nitrogen came when divers began descending below 200 feet and
nitrogen narcosis entered as a serious hazard. This narcosis, sometimes referred to as the rapture of the deep, was a result of the narcotic effects of nitrogen when under pressure. This narcosis is not evident when helium is used as the diluent (for oxygen) in deep diving.
Since recreational divers typically do not descend below 130 feet, the narcotic effect may be evident but is not particularly bothersome. Technical divers go deeper and therefore helium would be of value. Furthermore,
tech divers switch from heliox to nitrox mixtures below about 200 feet to speed decompression because nitrogen is taken in slower than helium is eliminated.
If there is not an advantage for heliox at depth shallower than 200 feet, and additional problem with helium is its
cost in comparison to compressed air. Frankly, there are not any advantages for a recreational scuba diver (<130 fsw) with a helium/oxygen mix compared to a nitrogen/oxygen mix.
{PS I was away at the NAUI meeting and am behind on these posts.}