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I'd been curious about the effect of off gassed nitrogen remaining in a CCR loop used for deco. If it accumulated enough to make the deco less effective, or if occasional venting was needed to keep the ppN2 down. Thanks. That you off gas enough helium to affect the physical volume of the loop is fascinating.
Taking just the nitrox case, if you are at a constant depth and your ppO2 is going down faster due to N2 off-gassing and you do not try to keep it high at say 1.4 but let it drop to say 1.2 by definition you've increased the ppN2 of the closed loop of gas you are using for deco and so decreased its effectiveness as you off-gas more and more N2 into it. How much, I do not know.
ETA: I imagine it is less effective by the difference between 1.4 and 1.2 ppO2 on nitrox at that depth. And I mean less effective on time, not on the effective use of the O2 available in the cylinder. My original curiosity came from the case of grabbing an O2 rebreather because of omitted OC air/nitrox deco and hanging at 20' on it. Over time you fill the loop with more and more N2 if you never vent gas, making it less and less of a pure O2 deco and more breathing the same N2 you flushed from tissues.
The effectiveness of deco is a function of inspired inert gas pressure against the tissues inert gas pressure. As you offgas into the loop, the pressure of inspired inert gas increases. I.e. a true EAN50 flush at 70ft is ppO2 of 1.5 and a ppN2 of 1.5. If you are coming off a dive and the ppO2 drops to say 1.2, then you are now breathing what is effectively EAN40 which is less effective than EAN50 because there isn't as much of a pressure gradient. Running min loop volume and maintaining it while you are offgasing is critical for efficient and effective deco. If you're riding the computer it is constantly tracking all of that anyway, but if you're running tables it can become a problem. Same at the 20ft stops, you're supposed to be breathing pure O2 at 1.6, but if you drop to 1.3 you are now breathing 80% instead of 100%. It compounds rather quickly. I don't know anyone running tables on CCR's, but it can affect the preplanned runtimes that are assuming you are at a stable ppO2.
Effectiveness of the O2 in your cylinder is part of the equation though because the more time you are in the water the more O2 you use, but also that the smaller the gradient between inspired ppN2/He and the pressure in the tissues the less effective/efficient the decompression itself is so the O2 isn't working as well as it normally would be if it was at 100% instead of 80%.
A 100ft dive for 150mins on EAN32 is not an uncommon cave dive. On a GF of 50/80 that calls for 45mins of deco on 100%. On 80% that's 54mins. It may not be that significant, but it adds up pretty quickly