Just to add a couple of centavos - if the purpose of the class is to give instruction to folks who have never dived or taken a Scuba class, IMHO Boyles law is by far the most important to discuss. Learning about nitrogen saturation, decompression, and oxygen toxicity is important, but I expect few people with no background would guess that an overexpansion injury or death therefrom could occur by taking a breath at 15 ft depth and then surfacing without exhaling. It is an eye opener to realize how much air expands / compresses between shallow depths and surface or vice versa.
One other minor and rather picky point - Charles' law isn't completely without application to diving, since water temperature can change significantly with depth. Certainly the hydrostatic pressure of the water is by far the greatest and most important effect, but the change in temperature will also play a minor role in the volume change of air in a BC for example. In practice it is negligible compared to the effect described by Boyle's law. And yes, Charles kept it simple by dealing with no pressure change, but the bottom line is he described changes in volume of gases with changes in temperature. In the end, the work of all of these folks combined to form the ideal and real gas laws.