Fwiw..I don't have a booster either. It is no problem to fill O2, nitrox, trimix etc...without a booster.
That's cool... like I said it's not even an issue here and 80% is just fine. Frankly the whole 80% vs. O2 thing is a bit of and off topic. Apologies to the OP for the side show.
Anyway, try adjusting your GF's and hopefully you should feel better.