I posted this account recently on a different thread, but I thought it might add some balance to this discussion....
The only experience I have with a serious DCI hit is this... as my buddy (tech dive) had a particularly nasty hit with these symptoms (plus severe weakness and bilateral leg immobility).
We were on a technical liveaboard trip, 2 days from land. The condition resolved after prolonged (3 hours) dry FO2 and hydration treatment. Victim made a complete recovery. (phew!).
The (deep air) dive went perfectly, including decompression, but symptoms presented immediately and severely on exiting the water.
The victim was using an adjustable 'comfort' harness and, subsequently, a dive doctor informed him that the most likely cause of the hit was due to having an over-tightened harness, coupled with arm immobility during prolonged decompression, that prevented effective off-gassing from his upper-limbs. This was based on the way that symptoms presented (chokes) immediately on releasing his shoulder straps after exit from the water. This was followed by extensive cutis marmorata (marbleized skin) around his torso that was noticed when he removed his wetsuit (very obvious and could not be confused with a common 'skin rash'). He then lost mobility in one leg and suffered fatige to the point of semi-consiousness.
Points to note;
1. Chamber evacuation was not an option (within 24 hours).
2. Casualty was effectively immbolized, with reduced consiousness.
3. Re-entering the casualty to the water would have been very risky.
4. Casualty was administered 100% O2, hydrated and laid supine.
5. Major DCI symptoms resolved within 3 hours.
6. Minor fatigue and ache remained for 12 hours.
7. Casualty was assessed by a dive doctor at a recompression chamber 18 hours after exiting the water.
8. Casualty did not require recompression treatment and recovered full health within 48 hours.
So, from my experience, in the event of a DCI hit (type I or II), the approved method of treatment using 100% O2 and hydration proven it's effectiveness.
Either method (surface O2 or IWR) could work and either may fail. The difference is that one method places the casualty in no further danger, wheras the other places them back into a situation where any number of complications could easily kill them.