@fxb that's what the RescuEAN's are for. Demand valves on medical regs are no less dangerous than trying to give breaths to an unconscious person with a scuba regulator. Frankly it may actually be less dangerous since there is an exhaust valve on there so it can't build up quite as much pressure. It's not an MTV-100 which I keep with me when teaching, but a RescuEAN with a BVM and non-rebreather mask work perfectly fine.
Ah, yes I had forgotten that the exhaust valve would still work while the regulator is being purged. So it seems like in the best case this technique would be ineffective as all or most of the gas would vent out to the sides, and in the worst case you may end up delivering a massive amount of air to the lungs and/or stomach causing further injury. I get what you're saying, and it might work, though I certainly would not want to try it (or have it tried on me). And you mentioned the demand valve like the ones DAN sells don't have an exhaust. This is true, but is there a way to start gas flow without a negative crack pressure (aside from MTV?) I can't recall that there is but may be mistaken.
Either way, the technique of positive-pressure ventilation is well beyond the scope of an AN class, even if you have Rescue and First Aid the topics on providing emergency oxygen there do not get into that.
Agree, the RescueEAN + BVM seems like a really great option and would cover pretty much any scenario, especially if a medical cylinder and regulator is not accessible or has been depleted. I'll have to get one of those... looks neat.
Anyway. I think if you've got an unconscious, non-breathing diver you've got bigger concerns than trying to cobble together a PPV system. If no MTV or BVM is available (and nobody trained to use them), better to use standard mouth-to-mouth rescue breaths with or without a barrier. (IMO)