A lot of people just do the math to find the "max mix" for their depth based on a 1.4ppo2.
Don't forget to also take into account the CNS clock and OTU's, of course, but there's two other things to consider.
First, is exceeding your max depth. I don't like to use the "max mix" if there is a risk you can exceed the MOD. It's nice to know you are diving a mix that is pretty good, but lets you go a few feet deeper than planned and still be within 1.4ppo2.
Secondly, is mix confusion. You do have an analyzer at home, and analyze each tank before you use it, right? Even so, I like to keep standard mixes so there isn't a risk of skipping analyzing and diving a 36% tank when I thought it was a 32% tank. It's just another layer to prevent any issues, so two systems and processes should keep me from mixing up gases.
That said, one of the big reasons I use 32% for dives even when 36% could work is, I don't NEED 36% to do the dive, and I rarely get gas anywhere that doesn't sell 32% banked, so 36% would be a hassle to get.