- being able to do the somersault is a skill you need
- also practice detaching/reattaching the inflator hose and adjusting the valve.
Otherwise, maintaining buoyancy (just practice, practice, practice) has already been addressed.
Mentally prepare your emergency procedures (e.g. what will you do if it floods and possibly gets heavy?) and get to know your drysuit well. Every suit has some quirks, e.g. water might leak in if you fold your neck cuff wrong or the gloves might be hard to attach without lube. If you're as forgetful as I am, plenty of small things will go wrong in the beginning, such as failure to fasten straps properly or entaglement issues when slipping in. Just be patient, do it during daylight and follow up on what you did wrong.
In the water, keep an eye on your trim and drag and adjust the weight distribution and fin length appropriately for maximum comfort. It's going to be different than in your wetsuit.
And of course watch the inflation level so you don't get squeezed.