Hello tbone.
I know this issue has been talked about a lot over the years, but I have never been able to find any evidence that it is a pragmatically relevant risk. We presented what we understand is known about the effect of prolonged oxygen exposure on lung diffusing capacity for gas in the Comprehensive Physiology paper that Ryan links to above (pages 180 - 181). A reasonable synthesis of that evidence would be that extreme oxygen exposures (beyond what is likely to be encountered in 99% of technical diving scenarios) can reduce lung diffusing capacity for gas, but that the changes seen even in technical dives that would be considered extreme are unlikely to disturb gas transfer to an extent that would materially affect the risk of DCS. For example, in the most comprehensive human experiment we cite, after exposure to 1.5 ATA of oxygen for about 18 hours, the lung's ability to diffuse carbon monoxide was only reduced by about 5%. After a technical dive where the exposure is typically much shorter (even for extreme dives) this effect would be smaller and there would be very little effect on DCS risk.
If you are aware of any relevant evidence we missed in that review I would be very interested to hear about it.
Simon M