First, Ox-Tox is a
potential risk at ANY elevated PO2.
Second, you expose yourself to that elevated PO2
any time you dive. This is true whether your Nitrox mix is EANx21 or EANx32.
Third, the entire "better gas" thing is nonsense too. If you don't trust the gas going in your lungs to be clean, you shouldn't be breathing it in the first place. Ditto for your tank's condition. I prefer NOT to breathe oil mist, thank you very much. As such I demand that I have very high quality gas ALL the time, and that my tanks be O2-clean ALL the time. Whether I put additional Oxygen in the mix therefore is of no material consequence in terms of the standards that my gear is maintained to.
Fourth, I am aware of
no documented Oxtox hits in recreational divers at a peak PO2 exposure under 1.4. There have been a few documented hits with exposures of 1.6. However, 1.6 is a commonly-accepted decompression PO2, and appears to be quite safe, as
when used for deco purposes there are very few reports of trouble. The "standard" for exposure in the recreational community is a PO2 of 1.4, and from the available accident analysis, it appears to be reliably safe in that there have been no recorded proven O2 hits at or under that exposure across millions of dives performed that were not potentiated by another factor (e.g. medication that one should simply not take while diving, and are just as likely to have caused the incident as the breathing gas itself.)
Whole-body (e.g. pulmonary) toxicity is simply not an issue in recreational exposures. I challenge you to find a set of profiles in recreational exposures that will exceed the NOAA whole-body limits, including credit back for time back on air at the surface during SIs. (It IS possible to do so on technical decompression dives; I'm talking about NDL recreational profiles here.)
The
nearly sole cause of O2 hits is a diver unintentionally (due to lack of personal analysis!) diving a "hot" mix, a technical diver breathing off the wrong (e.g. deco) bottle at depth, or a violation of the MOD.
Yes, O2 hits are possible, and if you have one at depth you are likely cooked. However, the entire CONVENTID thing is largely academic, since (1) the first symptom of a hit is VERY LIKELY to be a seizure, and (2) even if its not, the risk of the hit does NOT go away instantly; if you detect the symptoms ascending immediately to cut your PO2 and thus risk does not alleviate the possibility of the tox incident for several minutes. Getting 30 seconds of warning that you're about to die isn't all that helpful.
The
primary thing to know about O2 hits is that they must be
prevented, not "detected." The means for preventing them is to (1) ALWAYS
know what is in your breathing gas tank from personally witnessing its analysis or (ideally) doing it yourself, and (2) do
NOT exceed the MOD for the mix you are breathing.
If you know that, and compute your effective nitrogen loading (either by using a computer that does so or by manually doing so in order to use tables cut originally for air) then the "big lesson" for diving Nitrox is to breathe continuously!
BTW I
am Nitrox certified. The class was the biggest joke and waste of $150 that I've experienced in my diving career, and the resulting extra costs that shops try to hit you for annually thereafter with insane cylinder banding that are just continued insult. My personally-owned cylinders do not have Nitrox stickers on them and never will. I fill them myself, put contents labels on them, and nobody dives them without knowing what's in there and what that means. $10 for a big piece of vinyl to wrap around the top of the tank is beyond stupid and tells the diver NOTHING about the contents.
The two equations that are truly necessary to DIVE recreational Nitrox mixtures - under 40% FO2 - should be in EVERY BOW course. If you can't handle basic algebra, you have no business diving.
ALL tanks should be labelled as to (1) contents, (2) the fill pressure, (3) WHO filled it, and (4) WHEN it was filled. This way (1) you know what's in there, (2) who put it in there, (3) that it hasn't been used (because the pressure matches reasonably well) and (4) who your next of kin should go after if it turns out that the person who put it in there did something wrong, like filling a tank full of CO.
I personally won't dive a tank unless
I put the contents label on the tank, and either personally analyzed the mix or witnessed it being done so with a known-good analyzer.
If a tank has no contents label containing the above, it is not IMHO diveable and should be used to fill tires rather than your lungs. This PREVENTS mistakes and does away with silly tank decals which serve to provide no useful information.