Lots of interesting feedback. As I new diver diving for less than a year I'll sum up what I believe to be the reason in one wor which you also identified.
CURIOSITY
Curiosity is all well and good ... but if you can't invest the time and effort to learn how to satisfy your curiosity safely, then you have no business going there.
I'm aware of persons who've gone 200' on air
I'm aware of those people too. One of them was a friend of mine. He was 26 years old, and considered himself a pretty darn solid diver. They found his body half-buried in the mud at 205 fsw 10 months after he did his final dive. People say nice things like "well, at least he died doing something he loved." I'm pretty certain he wasn't loving his last moments of that dive.
and I have to say that topics like 02 toxicity should be taught on OW for the safety of all. I personally was aware of the danger at depth of 02 before I started diving and that has made me very aware of staying within rec limits when breathing air.
I prefer giving my students more realisitic reasons why they should stay within recreational limits ... like how easy it is to blow through a tank of gas when you're a new diver with a high consumption rate and struggling to do the simple things like maintain decent buoyancy control. Oxygen toxicity is a problem people don't have to worry about until they are experienced enough to be doing dives where they're pushing their PPO2 well beyond what OW divers should be doing. I prefer to focus new diver's attention on the things that will matter to them ... how to dive with a buddy, how to manage buoyancy control, how to pay attention to what's going on around you, how to not run out of air ... the little things that are the difference between having a great time or scaring the crap out of yourself.
I will happily train my divers about the dangers of oxygen toxicity when their diving reaches a level where it can matter. But for the OW diver it's a complete non-issue. If I even suspect that you're the sort of person who's going to push your OW training to the point where oxygen toxicity becomes a concern,we will be having a very serious discussion ... and if it doesn't go the way I think it should, then you'll be in a position to find a different instructor to complete your training.
The issue however is that we are getting persons involve in this sport and then setting limitations on what they can do without any real explanation or understanding.
I disagree. No responsible instructor will tell you to do something without telling you why it matters. And if you don't understand the "why" it's your responsibility to let your instructor know that's the case, so they can find a different way to help you understand. Once you do understand the "why", then it's your choice to either follow your training or not. If the latter, then I don't want you in any further classes with me ... because in this day and age it's a pretty sure bet that if you should exceed your training and end up dead, your surviving family members will sue me.
You ... and only you ... are responsible for the consequences of your choices.
I
If I tried that with my daughter I'm certain as soon as my back was turned that she'd be doing what I said not to do.
... and as a parent, I would fully expect you to hold her responsible for her actions and make her fully aware that her choices have consequences.
Humans are curious by nature and we need to explain the logic behind rec limits similar to what is done with nitrox. Every type of gas divers breathe has a max operating depth at which point it can become fatal. If we satisfy basic curiosities persons will seek training or mentors prior to engaging in activities beyond their level simply because they understand the risk.
I can think of a dozen or more good reasons why divers at the OW level should not exceed recreational depths. And I'm very good at explaining those reasons and describing why they're a bad idea. Oxygen toxicity is not among those reasons. It doesn't have to be ... if, at the OW level, you're putting yourself at a depth where it can be a concern, you've already broken several basic safety rules that you should have known better than to break ... and in the process demonstrated that your judgment is so poor that you should not ever have been certified in the first place.
... Bob (Grateful Diver)