Here is a benefit that I really like.why is 100% considered so much better when it only gives you an additional ~4 min of deco taking 80%? That seems pretty insignificant if you ask me. Unless I’m missing some other significant benefit?
When I am doing the 20 foot stop on pure O2, it is something of a PITA. If I allow myself to go to 19 feet, my computer gets mad at me for missing my deco stop. If I go below 21 feet, my computer gets mad at me for a high PPO2. When I am done with the 20 foot stop, it is a very relaxing feeling, because there is no benefit to going much shallower than that. The PPN2 will be 0.0 at any depth, so I don't need to get near 10 feet to maximize my gradient. Where I do most of my diving, our 10 foot stops are typically about 30 minutes, and rather than hover and stare at each other that time, we usually go for a very casual swim, and it is very nice not to particularly care how deep we are during that time.
If I were on 80%, I would want to do that entire 30+ extra minutes as close to 10 foot as I could, with my computer once more getting angry with me if I went to 9 feet. I could do it deeper, but that would not maximize the gradient, and I would have to have a longer stop.